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Excitation energies, oscillator strengths, and lifetimes of levels along the gold isoelectronic sequence

机译:沿金等电子序列的激发能,振荡器强度和能级寿命

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摘要

Energies of ns[1/2] (n= 6-9), np[j] (n = 6-8), nd[j] (n= 6-7), and 5f[j] states in neutral Au and Au-like ions with nuclear charges Z = 80 - 83 are calculated using relativistic many-body perturbation theory. Reduced matrix elements, oscillator strengths, transition rates and lifetimes are determined for the 30 possible nl[j]-n'l'[j'] electric-dipole transitions. Results for a limited number states ns[1/2], np[j] (n= 6-7) and 6d[j] are obtained in the relativistic single-double (SD) approximation, where single and double excitations of Dirac-Fock wave functions are included to all orders in perturbation theory. Using SD wave functions, accurate values are obtained for energies of the eight lowest states and for the fourteen possible electric-dipole matrix elements between these states. With the aid of the SD wave functions, we also determine transition rates and oscillator strengths for the fourteen transitions together with lifetimes of 6p[j], 7p[j], and 6d[j] levels. We investigate the hyperfine structure in HgII and TlIII. The hyperfine A-values are determined for 6s[1/2] and 6p[j] states in 199Hg+, 201Hg+, and 205Tl++ isotopes. These calculations provide a theoretical benchmark for comparison with experiment and theory.
机译:中性Au和ns [1/2](n = 6-9),np [j](n = 6-8),nd [j](n = 6-7)和5f [j]态的能量使用相对论多体摄动理论计算核电荷为Z = 80-83的类金离子。对于30种可能的nl [j] -n'l'[j']电偶极跃迁,确定了减少的矩阵元素,振荡器强度,跃迁速率和寿命。相对论状态ns [1/2],np [j](n = 6-7)和6d [j]的结果是通过相对论单双(SD)逼近获得的,其中Dirac-扰动理论中的所有阶都包括了福克波函数。使用SD波函数,可以获得八个最低状态的能量以及这些状态之间十四个可能的电偶极子矩阵元素的准确值。借助SD波函数,我们还可以确定14个跃迁的跃迁速率和振荡器强度,以及6p [j],7p [j]和6d [j]级的寿命。我们研究了HgII和TlIII中的超精细结构。确定了199Hg +,201Hg +和205Tl ++同位素中6s1 / 2和6p [j]状态的超精细A值。这些计算为与实验和理论比较提供了理论依据。

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  • 作者

    Safronova, U I; Johnson, W R;

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  • 年度 2004
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  • 原文格式 PDF
  • 正文语种 eng
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